摘要:
A method for the production of a nanocrystalline molybdenum mixed oxide, the use of the molybdenum mixed oxide as catalyst for chemical conversions, in particular for a conversion of acrolein to acrylic acid as well as a catalyst that contains the molybdenum mixed oxide.
摘要:
Bulk metallic catalysts comprised of a Group VIII metal and a Group VIB metal and methods for synthesizing bulk metallic catalysts are provided. The catalysts are prepared by a method wherein precursors of both metals are mixed and interacted with at least one organic acid, such as glyoxylic acid, dried, calcined, and sulfided. The catalysts are used for hydroprocessing, particularly hydrodesulfurization and hydrodenitrogenation, of hydrocarbon feedstocks.
摘要:
A shell catalyst for producing vinyl acetate monomer (VAM), comprising an oxidic porous catalyst support, formed as a shaped body, with an outer shell in which metallic Pd and Au are contained. To provide a shell catalyst for producing VAM which has a relatively high activity and can be obtained at relatively low cost, the catalyst support is doped with at least one oxide of an element selected from the group consisting of Li, P, Ca, V, Cr, Mn, Fe, Sr, Nb, Ta, W, La and the rare-earth metals.
摘要:
The present invention relates to a method for producing a shell catalyst which comprises a porous shaped catalyst support body with an outer shell in which at least one catalytically active species is present. In order to provide a shell catalyst production method by means of which shell catalysts can be produced, said shell catalysts having, over a comparatively large region of their shell thickness, a substantially uniform concentration of catalytically active species and having a substantially uniform shell thickness, what is proposed is a method using an device which is designed to generate, by means of a process gas, a fluid bed of shaped catalyst support bodies in which the shaped catalyst support bodies circulate elliptically or toroidally, preferably toroidally, comprising the steps of charging the device with shaped catalyst support bodies and generating a shaped catalyst support body fluid bed by means of a process gas, the shaped catalyst support bodies circulating elliptically or toroidally in the fluid bed, preferably toroidally; impregnating an outer shell of the shaped catalyst support body with a catalytically active species or precursor thereof by spraying the shaped catalyst support bodies circulating elliptically or toroidally in the fluid bed with a solution comprising a catalytically active species or a precursor thereof; drying the shaped catalyst support bodies sprayed with the solution.
摘要:
The present invention relates to a porous catalyst support, consisting of a material comprising a natural sheet silicate, wherein ZrO2 is contained distributed in the material. The present invention also relates to a process for the preparation of the catalyst support according to the invention and to a shell catalyst containing the catalyst support according to the invention and also the use of the catalyst according to the invention in particular for the preparation of vinyl acetate monomer (VAM).
摘要:
The present invention relates to a shell catalyst, a process for its preparation and also the use of the shell catalyst according to the invention.
摘要:
The present invention is directed to methods for making metal oxide compositions, specifically, metal oxide compositions having high surface area, high metal/metal oxide content, and/or thermal stability with inexpensive and easy to handle materials. In one embodiment, the present invention is directed to methods of making metal and/or metal oxide compositions, such as supported or unsupported catalysts. The method includes combining a metal precursor with an organic acid to form a mixture and calcining the mixture for a period of time sufficient to form a metal oxide material.
摘要:
The present invention addresses at least four different aspects relating to catalyst structure, methods of making those catalysts and methods of using those catalysts for making alkenyl alkanoates. Separately or together in combination, the various aspects of the invention are directed at improving the production of alkenyl alkanoates and VA in particular, including reduction of by-products and improved production efficiency. A first aspect of the present invention pertains to a unique palladium/gold catalyst or pre-catalyst (optionally calcined) that includes rhodium or another metal. A second aspect pertains to a palladium/gold catalyst or pre-catalyst that is based on a layered support material where one layer of the support material is substantially free of catalytic components. A third aspect pertains to a palladium/gold catalyst or pre-catalyst on a zirconia containing support material. A fourth aspect pertains to a palladium/gold catalyst or pre-catalyst that is produced from substantially chloride free catalytic components.
摘要:
The present invention is directed to nickel compositions and methods for making nickel oxide compositions, specifically, such metal oxide compositions having high surface area, high metal/metal oxide content, and/or thermal stability with inexpensive and easy to handle materials.
摘要:
The invention relates to noble metal-free nickel catalysts that exhibit both high activity and selectivity to hydrogen generation and carbon monoxide oxidation. The noble metal-free water gas shift catalyst of the invention comprises Ni in either a supported or a bulk state and at least one of Ge, Cd, In, Sn, Sb, Te, Pb, their oxides and mixtures thereof.