摘要:
An exhaust system for a diesel engine is provided. The exhaust system includes a component body with a surface, and a surface treatment disposed on some of the surface or all of the surface. The surface treatment is disposed so as to receive Diesel Exhaust Fluid (DEF) injected into the exhaust system during operation of the diesel engine. The surface treatment facilitates increased heat transfer to the received DEF to promote water evaporation and urea thermolysis of the received DEF.
摘要:
STA-20, a molecular sieve having a new framework type, is described. STA-20AP (as prepared) can have an alkyl amine, such as trimethylamine, and 1,6-(1,4-diazabicyclo[2.2.2]octane) hexyl cations (from diDABCO-C6) as SDAs. A lower alkyl ammonium hydroxide, such as tetrabutylammonium hydroxide, can be used as a pH modifier for making SAPO STA-20. A calcined product, STA-20C, formed from as made STA-20 is also described. Methods of preparing STA-20, activating STA-20 by calcination, and metal containing calcined counterparts of STA-20 are described along with methods of using STA-20 and metal containing calcined counterparts of STA-20 in a variety of processes, such as treating exhaust gases and converting methanol to olefins are described.
摘要:
An exhaust system for a diesel engine is provided. The exhaust system includes a component body with a surface, and a surface treatment disposed on some of the surface or all of the surface. The surface treatment is disposed so as to receive Diesel Exhaust Fluid (DEF) injected into the exhaust system during operation of the diesel engine. The surface treatment facilitates increased heat transfer to the received DEF to promote water evaporation and urea thermolysis of the received DEF.
摘要:
The present invention relates to a process for the preparation of a zeolitic material having a structure comprising YO2 and optionally comprising X2O3, preferably comprising YO2 and X2O3, wherein said process comprises the steps of (1) providing a mixture comprising one or more ammonium compounds of which the ammonium cation has the formula (I): [R1R2NR3R4]+ (I) and further comprising one or more sources for YO2 and one or more sources for X2O3; (2) crystallizing the mixture provided in (1); wherein Y is a tetravalent element, and X is a trivalent element, and wherein in formula (I) R1 and R2 are independently from one another derivatized or underivatized methyl, and R3 and R4 are independently from one another derivatized or underivatized (C3-C5)alkyl, and wherein the molar ratio of ammonium cation having the formula (I) to Y in the mixture provided in step (1) and crystallized in step (2) is equal to or greater than 0.25.
摘要:
Aspects of the present invention relate to a process for the preparation of a zeolitic material having a CHA-type framework structure comprising YO2 and X2O3, wherein said process comprises the steps of: (1) providing a mixture comprising one or more sources for YO2, one or more sources for X2O3, and one or more tetraalkylammonium cation R1R2R3R4N+-containing compounds as structure directing agent; (2) crystallizing the mixture obtained in step (1) for obtaining a zeolitic material having a CHA-type framework structure; wherein Y is a tetravalent element and X is a trivalent element, wherein R1, R2, and R3 independently from one another stand for alkyl, wherein R4 stands for cycloalkyl, and wherein the mixture provided in step (1) does not contain any substantial amount of a source for Z2O5, wherein Z is P, as well as to zeolitic materials which may be obtained according to the inventive process and to their use.
摘要:
System and methods for reducing secondary emissions in an exhaust stream from an internal combustion engine are disclosed. The systems and methods include a filtration device positioned downstream from an SCR catalyst of an aftertreatment system disposed in the exhaust system. The filtration device can also be used for particulate filter diagnostics and for treatment of ammonia slip.
摘要:
The present disclosure relates to an exhaust gas after-treatment apparatus and an exhaust gas after-treatment method including a selective catalytic reduction (SCR) process, and more particularly, to an exhaust gas after-treatment apparatus having improved durability and an exhaust gas after-treatment method, which selectively determine to operate a selective catalyst reducing part and an ammonia oxidation catalyst (AOC) part on the basis of a generated amount and a rate of change of a nitrogen compound (NOx) in exhaust gas.
摘要:
A method for producing a catalyst using an additive layer method includes: (i) forming a layer of a powdered catalyst or catalyst support material, (ii) binding or fusing the powder in said layer according to a predetermined pattern, (iii) repeating (i) and (ii) layer upon layer to form a shaped unit, and (iv) optionally applying a catalytic material to said shaped unit.
摘要:
An ammonia-engine system is capable of supplying an ammonia cracking catalyst with a temperature necessary to promote a reaction even during low load operation in which a temperature of an exhaust gas from an ammonia engine is lower than an operating temperature of the ammonia cracking catalyst. In an ammonia-engine system provided with an ammonia engine (2) using ammonia as fuel and an ammonia cracking device (5) including an ammonia cracking catalyst that cracks ammonia and cracking ammonia to produce hydrogen, an ammonia oxidizing device (4) is provided between the ammonia engine (2) and the ammonia cracking device (5).
摘要:
An aftertreatment system utilizes chemical reactions to treat an exhaust gas flow. A device for use within an aftertreatment system includes a platinum-free ammonia oxidation catalyst comprising palladium to treat ammonia slip in the exhaust gas flow. In one embodiment, the catalyst includes a Pd/Cu/SAPO-34 catalyst used within a selective catalytic reduction device or in a device downstream of the selective catalytic reduction device.
摘要翻译:后处理系统利用化学反应来处理废气流。 在后处理系统中使用的装置包括含铂的无铂氨氧化催化剂,用于处理废气流中的氨滑移。 在一个实施方案中,催化剂包括在选择性催化还原装置内或在选择性催化还原装置下游的装置中使用的Pd / Cu / SAPO-34催化剂。