Air activated organotin catalysts for polyurethane synthesis
    82.
    发明授权
    Air activated organotin catalysts for polyurethane synthesis 有权
    用于聚氨酯合成的空气活化有机锡催化剂

    公开(公告)号:US07919423B2

    公开(公告)日:2011-04-05

    申请号:US12698288

    申请日:2010-02-02

    Abstract: This invention relates to an organotin-based catalyst system for polyurethane synthesis that is useful in coatings applications. The catalyst has low activity in the absence of oxygen. When a coating mixture comprising the catalyst is sprayed and/or applied to a substrate as a thin film in air, the catalyst is activated. For solvent-based refinish systems comprising hydroxyl and isocyanate species at high solids levels, the catalyst system therefore provides extended viscosity stability, i.e., pot life.

    Abstract translation: 本发明涉及用于聚氨酯合成的有机锡基催化剂体系,其可用于涂料应用。 催化剂在不存在氧的情况下具有低活性。 当包含催化剂的涂料混合物在空气中作为薄膜喷涂和/或施加到基材上时,催化剂被活化。 对于含有高固体含量的羟基和异氰酸酯物质的基于溶剂的修补体系,催化剂体系因此提供了延长的粘度稳定性,即适用期。

    Visible light-responsive photocatalyst, method for producing same, photocatalyst coating agent using same, and photocatalyst dispersion
    83.
    发明授权
    Visible light-responsive photocatalyst, method for producing same, photocatalyst coating agent using same, and photocatalyst dispersion 有权
    可见光响应性光催化剂,其制造方法,使用该光催化剂的光催化剂涂布剂和光催化剂分散体

    公开(公告)号:US07820584B2

    公开(公告)日:2010-10-26

    申请号:US12225011

    申请日:2007-03-13

    Abstract: Disclosed is a photocatalyst which is excited when irradiated with visible light and exhibits high photocatalytic activity stably. This photocatalyst has a white hue with little yellow tint. Specifically, titanium oxide particles and a halogenated platinum compound are heated and mixed in a liquid medium, so that the surfaces of the titanium oxide particles are loaded with the halogenated platinum compound; then the pH of the liquid medium is adjusted to 5 or less; and after that, the liquid medium is neutralized if necessary. By such a process, there can be produced a photocatalyst having a specific surface area of 10-100 m2/g, wherein the surfaces of the titanium oxide particles are loaded with the halogenated platinum compound and the b* value of the powder color according to the Hunter color system is not more than 6.

    Abstract translation: 公开了一种当用可见光照射并且稳定地表现出高光催化活性时被激发的光催化剂。 这种光催化剂具有黄色色调的白色色调。 具体地说,将氧化钛颗粒和卤化铂化合物在液体介质中加热混合,以使二氧化钛颗粒的表面装载卤化铂化合物; 然后将液体介质的pH调节至5以下; 之后,根据需要中和液体介质。 通过这样的方法,可以制造比表面积为10〜100m 2 / g的光催化剂,其中,氧化钛粒子的表面装载有卤化铂化合物,粉末颜色的b *值根据 猎人色系不超过6。

    SOLID SOLUTIONS AND METHODS OF MAKING THE SAME
    87.
    发明申请
    SOLID SOLUTIONS AND METHODS OF MAKING THE SAME 审中-公开
    固体溶液及其制备方法

    公开(公告)号:US20090246109A1

    公开(公告)日:2009-10-01

    申请号:US12240170

    申请日:2008-09-29

    Abstract: A composite single phase crystalline mixed metal oxide NOx scavenger formed of a solid solution, wherein the solid solution has a well defined single phase crystalline structure, as determined by conventional x-ray Diffraction method; and, a NOx scavenger disposed within the single phase oxide structure, without formation of additional X-ray discrete phase, wherein the NOx scavenger is formed from oxides of an element selected from the group consisting of alkali metals, alkaline earth metals, transition metals, rare earth metals and mixtures thereof. The aforementioned single phase oxide may further posses a cubic fluorite structure and said composite cubic oxide NOx scavenger may be advantageously applied to the control of emissions, of both gaseous and solid or particulate nature, from internal combustions especially engines operating under the principle of compression ignition.

    Abstract translation: 由固溶体形成的复合单相结晶混合金属氧化物NO x清除剂,其中固溶体具有良好限定的单相晶体结构,如通过常规x射线衍射法测定的; 以及设置在单相氧化物结构内的NOx清除剂,而不形成额外的X射线离散相,其中所述NOx清除剂由选自碱金属,碱土金属,过渡金属, 稀土金属及其混合物。 上述单相氧化物还可以具有立方萤石结构,并且所述复合立方氧化物NOx清除剂可以有利地应用于控制气体和固体或颗粒性质的排放物,来自内部燃烧,特别是在压缩点火原理下运行的发动机 。

    Methods of making and using a selective hydrogenation catalyst
    90.
    发明申请
    Methods of making and using a selective hydrogenation catalyst 有权
    制备和使用选择性氢化催化剂的方法

    公开(公告)号:US20050137433A1

    公开(公告)日:2005-06-23

    申请号:US10741800

    申请日:2003-12-19

    CPC classification number: C07C5/05 C07C5/09 C07C2523/66

    Abstract: In an embodiment, a method of hydrogenating a highly unsaturated hydrocarbon to an unsaturated hydrocarbon includes contacting the highly unsaturated hydrocarbon with a catalyst in the presence of hydrogen. The catalyst comprises palladium and an inorganic support having a surface area of from about 4.5 to about 20 m2/g, or alternatively 5 to 14.5 m2/g. The inorganic support may comprise α-alumina treated with a fluoride source. The palladium may be primarily disposed near the surface of the support. In addition, the catalyst may comprise silver distributed throughout the support. In another embodiment, a method of making the foregoing selective hydrogenation catalyst includes contacting a fluorine-containing compound with an inorganic support, heating the support, and adding palladium to the inorganic support. After adding palladium to the support, the support can then be heated again, followed by adding silver to and then heating the support once again.

    Abstract translation: 在一个实施方案中,将高度不饱和烃氢化成不饱和烃的方法包括在氢的存在下使高度不饱和烃与催化剂接触。 催化剂包括钯和无机载体,其表面积为约4.5至约20m 2 / g,或者5至14.5m 2 / g。 无机载体可以包括用氟化物源处理的α-氧化铝。 钯可以主要设置在支撑体的表面附近。 此外,催化剂可以包含分布在整个载体上的银。 在另一个实施方案中,制备上述选择性氢化催化剂的方法包括使含氟化合物与无机载体接触,加热载体,并向无机载体中加入钯。 向载体中加入钯后,再次加热载体,然后再加入银,然后再次加热载体。

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