Method for cleaning PZT thin film
    15.
    发明授权
    Method for cleaning PZT thin film 失效
    PZT薄膜清洗方法

    公开(公告)号:US06391119B1

    公开(公告)日:2002-05-21

    申请号:US09348477

    申请日:1999-07-07

    CPC classification number: H01L21/02071 H01L21/31111 H01L21/31691

    Abstract: A method for cleaning a PZT thin film using an etchant is provided. The method employs a combination of HF (or buffered oxide etchant (BOE)) and acetic acid, or a combination of HF(BOE), acetic acid and alcohol, as an etchant to thus reduce an etching rate of a PZT thin film, which is greatly dependent on the density of HF, thereby etching the PZT thin film to a finer dimension of thickness of 100Å or less using the etchant. Therefore, only secondary phase crystals or etching damaged layers on the surface of the PZT thin film can be eliminated.

    Abstract translation: 提供了使用蚀刻剂清洗PZT薄膜的方法。 该方法采用HF(或缓冲氧化物蚀刻剂(BOE))和乙酸或HF(BOE),乙酸和醇的组合作为蚀刻剂的组合,从而降低PZT薄膜的蚀刻速率, 很大程度上取决于HF的密度,从而使用蚀刻剂将PZT薄膜蚀刻到厚度为100埃或更小的更细的尺寸。 因此,可以仅消除PZT薄膜表面上的次相晶体或蚀刻损伤层。

    Ferroelectric capacitor and method of manufacturing the same
    17.
    发明授权
    Ferroelectric capacitor and method of manufacturing the same 失效
    铁电电容器及其制造方法

    公开(公告)号:US08257984B2

    公开(公告)日:2012-09-04

    申请号:US11319555

    申请日:2005-12-29

    Abstract: A ferroelectric capacitor and a method of manufacturing the same are provided, wherein the ferroelectric capacitor of a semiconductor device, which sequentially includes a lower electrode, a ferroelectric layer, and an upper electrode on a conductive layer connected to a transistor formed on a semiconductor substrate, includes an oxidation preventing layer between the conductive layer and the lower electrode. The oxidation preventing layer prevents the conductive layer from being oxidized during high-temperature heat treatment of the ferroelectric layer. Accordingly, the oxidation resistivity of the interfaces of the conductive layer, used as a storage node, and the lower electrode, which faces the conductive layer, increases, so a temperature at which a ferroelectric thin layer is formed can be also increased. Consequently, a ferroelectric thin layer having excellent characteristics may be obtained.

    Abstract translation: 提供了一种强电介质电容器及其制造方法,其中,在连接到形成在半导体衬底上的晶体管的导电层上依次包括下电极,铁电体层和上电极的半导体器件的强电介质电容器 包括在导电层和下电极之间的氧化防止层。 氧化防止层防止了导电层在铁电层的高温热处理期间被氧化。 因此,用作存储节点的导电层和面向导电层的下电极的界面的氧化电阻增加,因此也可以增加形成铁电薄层的温度。 因此,可以获得具有优异特性的铁电薄层。

    Ferroelectric thin film and device including the same
    19.
    发明授权
    Ferroelectric thin film and device including the same 有权
    铁电薄膜和包括它的装置

    公开(公告)号:US07560042B2

    公开(公告)日:2009-07-14

    申请号:US11819425

    申请日:2007-06-27

    Abstract: A composition for forming a ferroelectric thin film includes: a PZT sol-gel solution including at least one of: a whole or partial hydrolysate of a lead precursor and a whole or partial hydrolyzed and polycondensated product thereof; a whole or partial hydrolysate of a zirconium precursor, a whole or partial hydrolyzed and polycondensated product thereof, and a zirconium complex having at least one hydroxy ion and at least one non-hydrolyzable ligand; and a whole or partial hydrolysate of a titanium precursor, a whole or partial hydrolyzed and polycondensated product thereof, and a titanium complex having at least one hydroxyl ion and at least one non-hydrolyzable ligand; and a Bi2SiO5 sol-gel solution including at least one of: a whole or partial hydrolysate of a silicon precursor and a whole or partial hydrolyzed and polycondensated product thereof, and a resultant obtained by refluxing triphenyl bismuth as a bismuth precursor.

    Abstract translation: 用于形成铁电薄膜的组合物包括:PZT溶胶 - 凝胶溶液,其包含铅前体的全部或部分水解产物及其全部或部分水解缩聚产物中的至少一种; 锆前体的全部或部分水解产物,其全部或部分水解和缩聚产物,以及具有至少一个羟基离子和至少一种不可水解配体的锆络合物; 以及钛前体,其全部或部分水解缩聚产物和具有至少一个羟基离子和至少一个不可水解配体的钛络合物的全部或部分水解产物; 和包含硅前体的全部或部分水解产物及其全部或部分水解和缩聚产物中的至少一种的Bi 2 SiO 5溶胶 - 凝胶溶液,以及通过回流作为铋前体的三苯基铋得到的产物。

    Ferroelectric thin film and device including the same
    20.
    发明申请
    Ferroelectric thin film and device including the same 有权
    铁电薄膜和包括它的装置

    公开(公告)号:US20080237551A1

    公开(公告)日:2008-10-02

    申请号:US11819425

    申请日:2007-06-27

    Abstract: A composition for forming a ferroelectric thin film includes: a PZT sol-gel solution including at least one of: a whole or partial hydrolysate of a lead precursor and a whole or partial hydrolyzed and polycondensated product thereof; a whole or partial hydrolysate of a zirconium precursor, a whole or partial hydrolyzed and polycondensated product thereof, and a zirconium complex having at least one hydroxy ion and at least one non-hydrolyzable ligand; and a whole or partial hydrolysate of a titanium precursor, a whole or partial hydrolyzed and polycondensated product thereof, and a titanium complex having at least one hydroxyl ion and at least one non-hydrolyzable ligand; and a Bi2SiO5 sol-gel solution including at least one of: a whole or partial hydrolysate of a silicon precursor and a whole or partial hydrolyzed and polycondensated product thereof, and a resultant obtained by refluxing triphenyl bismuth as a bismuth precursor.

    Abstract translation: 用于形成铁电薄膜的组合物包括:PZT溶胶 - 凝胶溶液,其包含铅前体的全部或部分水解产物及其全部或部分水解缩聚产物中的至少一种; 锆前体的全部或部分水解产物,其全部或部分水解和缩聚产物,以及具有至少一个羟基离子和至少一种不可水解配体的锆络合物; 以及钛前体,其全部或部分水解缩聚产物和具有至少一个羟基离子和至少一个不可水解配体的钛络合物的全部或部分水解产物; 和包含硅前体的全部或部分水解产物及其全部或部分水解和缩聚产物中的至少一种的Bi 2 SiO 5溶胶 - 凝胶溶液, 和通过回流作为铋前体的三苯基铋获得的结果。

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