公开(公告)号：US09914111B1

公开(公告)日：2018-03-13

申请号：US15461490

申请日：2017-03-17

Applicant: Wuhu Gefeng Green Technology Research Center Co., Ltd. ,  Shandong Wuzhou Detection Co., Ltd.

Inventor： Xiangdong Feng ,  Menglu Shi ,  Wengui Zhang ,  Huanghe Wu ,  Weiwei Liang ,  Zhifeng Lan ,  Jian You ,  Changlu Zhang

IPC: B01J20/24 ,  B01J20/16 ,  B01J20/30 ,  C02F1/28 ,  C02F101/10

CPC classification number: B01J20/24 ,  B01J20/165 ,  B01J20/3007 ,  B01J20/3014 ,  B01J20/3021 ,  C02F1/281 ,  C02F1/286 ,  C02F1/288 ,  C02F2101/10

Abstract: The present invention relates to a mercury-containing wastewater treatment technology field, in particular to an attapulgite-crosslinked chitosan composite adsorbent and its solid-phase synthetic method. The attapulgite-crosslinked chitosan composite mercury adsorbent in the invention is synthesized by the method of adding chitosan and glutaraldehyde in batches. In consideration of the limited solubility of chitosan, batch addition can not only dissolve chitosan, but also minimize the use of organic acid, resulting in less discharge of wastewater and waste gas, which is suitable for large-scale industrial production. The prepared mercury adsorbent can be applied to the removal of mercury ions in the wastewater owing to the excellent adsorptive property and regeneration performance. Meanwhile, the solid-phase synthetic procedure for preparing the mercury adsorbent is simple, easy to handle and environmental-friendly. Moreover, the product cost is greatly reduced due to the use of attapulgite.

公开(公告)号：US09868800B2

公开(公告)日：2018-01-16

申请号：US15305971

申请日：2015-04-24

Applicant: NIPPON SHOKUBAI CO., LTD.

Inventor： Shinichi Fujino ,  Kunihiko Ishizaki ,  Satoshi Matsumoto

IPC: C08F120/06 ,  C08F20/06 ,  C08F2/01 ,  C08F2/10 ,  B01J20/26 ,  B01J20/30

CPC classification number: C08F120/06 ,  B01J20/261 ,  B01J20/265 ,  B01J20/267 ,  B01J20/3014 ,  C08F2/01 ,  C08F2/10 ,  C08F20/06

Abstract: A method for producing polyacrylic acid (salt)-based water-absorbing resin includes a step of polymerizing an acrylic acid (salt)-based aqueous monomer solution, the polymerization step involving use of a polymerization reaction apparatus including a polymerization reaction unit covered with a casing, the polymerization step involving a polymerization reaction under internal pressure of the polymerization reaction unit, the internal pressure being slightly reduced and having a pressure reduction level of more than 0 kPa and not more than 10 kPa relative to the ambient pressure at the periphery of the polymerization reaction unit.

公开(公告)号：US09623363B2

公开(公告)日：2017-04-18

申请号：US13673009

申请日：2012-11-09

Applicant: Centre National de la Recherche Scientifique ,  IFP Energies nouvelles

Inventor： Vincent Girard ,  Delphine Bazer-Bachi ,  David Chiche ,  Arnaud Baudot ,  Christophe Geantet

IPC: B01D53/48 ,  B01D53/02 ,  B01J20/06 ,  B01D53/52 ,  C01B3/56 ,  C10K1/00 ,  C10K1/32 ,  B01J20/30 ,  B01J20/34 ,  B01D53/82 ,  B01D53/83

CPC classification number: B01D53/02 ,  B01D53/48 ,  B01D53/52 ,  B01D53/82 ,  B01D53/83 ,  B01D2253/1124 ,  B01D2257/306 ,  B01D2257/308 ,  B01J20/06 ,  B01J20/3007 ,  B01J20/3014 ,  B01J20/3078 ,  B01J20/3433 ,  B01J20/3458 ,  B01J20/3491 ,  B01J2220/42 ,  C01B3/56 ,  C01B2203/0485 ,  C10K1/004 ,  C10K1/32

Abstract: A process for capturing sulphur impurities present in gas feeds containing H2 and/or CO: a. desulphurization with a retaining material containing an active phase, b. optionally, rendering the sulphurized retaining material inert, c. oxidative regeneration of the retaining material, d. optionally, rendering the regenerated retaining material inert, and e. desulphurization with the retaining material that has been regenerated and rendered inert, and regenerating the retaining material.

公开(公告)号：US20160325226A1

公开(公告)日：2016-11-10

申请号：US15108968

申请日：2014-12-30

Applicant: BEIJING SJ ENVIRONMENTAL PROTECTION AND NEW MATERIAL CO., LTD.

Inventor： Liying Li ,  Wenwen SONG ,  Wenjun MAO ,  Zhimin ZHANG ,  Boshu LIU ,  Zhenyi Liu

IPC: B01D53/80 ,  B01J21/16 ,  B01J23/78 ,  B01J37/00 ,  B01J37/04 ,  B01J20/30 ,  B01J37/06 ,  B01J20/12 ,  B01J20/04 ,  B01J20/08 ,  B01J20/02 ,  B01D53/48 ,  B01J37/08

CPC classification number: B01D53/80 ,  B01D53/485 ,  B01D2251/602 ,  B01D2257/308 ,  B01J20/0229 ,  B01J20/041 ,  B01J20/08 ,  B01J20/12 ,  B01J20/3007 ,  B01J20/3014 ,  B01J20/3071 ,  B01J20/3078 ,  B01J20/3085 ,  B01J21/04 ,  B01J21/063 ,  B01J21/16 ,  B01J23/78 ,  B01J37/0009 ,  B01J37/0036 ,  B01J37/031 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  B01J37/088

Abstract: Provided is a high-concentration carbonyl sulfide conversion-absorption type desulfurizer for use at medium-low temperature and preparation method thereof. The desulfurizer comprises 50%-75% magnetic iron oxide red (Fe21.333O32), 5%-10% alkali metal oxide (K2O), 5-35% anatase TiO2, and 5-10% shaping binder. The method of preparing the desulfurizer comprises: uniformly mixing a metatitanic acid prepared using ferrous sulfate recycled as a by-product from titanium dioxide production with K2CO3, calcining to activate at 500° C.-700° C., mixing with the magnetic iron oxide red and binder, roll molding at room temperature to form balls which are dried at 100° C.-150° C. to obtain the desulfurizer. The desulfurizer has a hydrolysis conversion of carbonyl sulfide higher than 99%, and has a higher sulfur capacity more than 25%.

Abstract translation: 提供了用于中低温的高浓度硫化羰转化吸收型脱硫剂及其制备方法。 脱硫剂包括50％-75％的磁性氧化铁红（Fe21.333O32），5％-10％的碱金属氧化物（K2O），5-35％的锐钛型TiO 2和5-10％的成型粘合剂。 制备脱硫剂的方法包括：将以二氧化钛生产的副产物再循环的硫酸亚铁制备的偏钛酸与K 2 CO 3均匀混合，煅烧以在500℃-700℃下活化，与磁性氧化铁 红色和粘合剂，在室温下成型，形成在100℃-150℃下干燥以获得脱硫剂的球。 脱硫剂具有高于99％的羰基硫化物的水解转化率，硫含量高于25％。

公开(公告)号：US20150352520A1

公开(公告)日：2015-12-10

申请号：US14399013

申请日：2013-04-19

Applicant: ARCHER DANIELS MIDLAND COMPANY

Inventor： Oscar Suarez-Hernandez

IPC: B01J20/26 ,  C08J7/04 ,  B01J20/30 ,  C08J3/24 ,  B01J20/22 ,  B01J20/32

CPC classification number: B01J20/267 ,  B01J20/223 ,  B01J20/3014 ,  B01J20/3078 ,  B01J20/3208 ,  C08J3/24 ,  C08J3/245 ,  C08J7/04 ,  C08J2333/02 ,  C08J2333/26 ,  C08J2403/06

Abstract: A dual-surface treated composite superabsorbent particle comprising a polycarboxylate polymer (e.g., saponified polyacrylamide) and a carboxylated starch polymer is disclosed. The surface of the particle is cross linked through esterification with a C2-C4 polyol exemplified with glycerol. In addition, the surface region is crosslinked through ionic bonds with a trivalent metal ion exemplified with aluminum. In a critical method of making, the acidification of the surface with the polyol occurs prior to treatment with the trivalent metal ion, which results is a hybrid particle that can include up to about 40% of carboxymethyl starch yet exhibit a FSC of at least 47 g/g, a CRC of at least 27 g/g, an AUL of at least 18 g/g under a load of 0.7 psi, and a SFR of at least 180 ml/min. Also disclosed is a method of making that includes a surface esterification prior to aluminum treatment.

Abstract translation: 公开了一种包含多羧酸盐聚合物（例如皂化聚丙烯酰胺）和羧化淀粉聚合物的双表面处理复合超吸收颗粒。 颗粒的表面通过酯化与C2-C4多元醇交联，以甘油为例。 此外，表面区域通过离子键与以铝为例列举的三价金属离子交联。 在制备的关键方法中，用三元金属离子处理之前，用多元醇进行表面酸化发生，这是一种杂化颗粒，其可以包括高达约40％的羧甲基淀粉，但表现出至少47的FSC g / g，至少27g / g的CRC，在0.7psi负载下至少18g / g的AUL和至少180ml / min的SFR。 还公开了一种制备方法，其包括在铝处理之前的表面酯化。

公开(公告)号：US20150191292A1

公开(公告)日：2015-07-09

申请号：US14418655

申请日：2013-08-01

Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.

Inventor： Natsuko Matsushita ,  Emi Ishihara ,  Hirokazu Tanaka ,  Tatsuo Iwai

IPC: B65D81/26

CPC classification number: B65D81/266 ,  A23L3/3436 ,  B01D53/02 ,  B01D53/14 ,  B01D53/82 ,  B01D53/8671 ,  B01D2257/104 ,  B01J20/0225 ,  B01J20/0229 ,  B01J20/0248 ,  B01J20/261 ,  B01J20/28026 ,  B01J20/28033 ,  B01J20/2805 ,  B01J20/28059 ,  B01J20/3014 ,  B01J20/3085 ,  B01J20/3204 ,  B01J20/3236 ,  B01J2220/46 ,  B22F1/00 ,  B22F1/0011 ,  B22F1/0088 ,  B22F1/02 ,  B22F9/04 ,  B22F2003/1014 ,  B22F2998/10 ,  B22F2999/00 ,  C08K3/08 ,  C08K3/10 ,  C22C1/02 ,  C22C33/04 ,  C22C38/06 ,  C23F1/00

Abstract: A process for producing an oxygen absorbing agent includes treating an alloy with an aqueous solution of an acid or an alkali, the alloy including at least one transition metal selected from the group consisting of manganese, iron, platinum, and copper group metals and at least one metal selected from the group consisting of aluminum, zinc, tin, lead, magnesium, and silicon to elute and remove at least a part of the component; and subjecting the alloy obtained by removing at least a part of the component in the alloy to treatment with an aqueous solution of a salt of an inorganic acid or a salt of an organic acid that can form a salt with the transition metal as the component, to form a metal salt in at least a part of the surface of the alloy.

Abstract translation: 一种制备氧吸收剂的方法包括用酸或碱的水溶液处理合金，所述合金包括至少一种选自由锰，铁，铂和铜族金属组成的组的过渡金属，并且至少 选自由铝，锌，锡，铅，镁和硅组成的组中的一种金属，以洗脱并除去至少一部分组分; 并且将通过除去合金中的至少一部分成分而获得的合金用无机酸盐或与过渡金属形成盐的有机酸的盐的水溶液作为组分进行处理， 以在合金的至少一部分表面形成金属盐。

公开(公告)号：US20150034561A1

公开(公告)日：2015-02-05

申请号：US14349081

申请日：2012-09-12

Applicant: Fabien Porcheron ,  Karin Barthelet ,  Arnaud Baudot ,  Antoine Daudin ,  Marc-Antoine Lelias ,  Yannick Gelie ,  Alexandre Nicolaos

Inventor： Fabien Porcheron ,  Karin Barthelet ,  Arnaud Baudot ,  Antoine Daudin ,  Marc-Antoine Lelias ,  Yannick Gelie ,  Alexandre Nicolaos

IPC: B01J20/08 ,  C10G25/00 ,  B01J20/28 ,  C10L3/10 ,  B01D15/10 ,  B01J20/32

CPC classification number: B01J20/08 ,  B01D15/10 ,  B01D53/02 ,  B01D53/64 ,  B01D2251/60 ,  B01D2253/104 ,  B01D2253/1128 ,  B01D2253/25 ,  B01D2253/31 ,  B01D2253/311 ,  B01D2256/24 ,  B01D2257/602 ,  B01D2258/0283 ,  B01J20/0218 ,  B01J20/0225 ,  B01J20/0237 ,  B01J20/0285 ,  B01J20/28004 ,  B01J20/28016 ,  B01J20/28047 ,  B01J20/28057 ,  B01J20/28059 ,  B01J20/28061 ,  B01J20/28069 ,  B01J20/28071 ,  B01J20/28073 ,  B01J20/28088 ,  B01J20/3007 ,  B01J20/3014 ,  B01J20/3078 ,  B01J20/3085 ,  B01J20/3204 ,  B01J20/3236 ,  C10G25/003 ,  C10L3/101 ,  C10L2290/541 ,  Y10T428/2982

Abstract: The present invention concerns the elimination of heavy metals, in particular mercury and possibly arsenic and lead, present in a gaseous or liquid effluent by means of a capture mass comprising a support essentially based on alumina obtained by the gel method and at least one element selected from the group constituted by copper, molybdenum, tungsten, iron, nickel and cobalt. The invention is advantageously applicable to the treatment of gas of industrial origin, synthesis gas, natural gas, gas phase condensates and liquid hydrocarbon feeds.

Abstract translation: 本发明涉及通过包含基本上由凝胶法获得的氧化铝的载体和选择的至少一种元素的捕获物质来消除存在于气体或液体流出物中的重金属，特别是汞和可能的砷和铅。 由铜，钼，钨，铁，镍和钴构成的组。 本发明有利地适用于工业原料气，合成气，天然气，气相冷凝物和液态烃进料的处理。

公开(公告)号：US20120107201A1

公开(公告)日：2012-05-03

申请号：US13260512

申请日：2009-03-27

Applicant: Hyun-Joong Kim ,  Yasushi Shioya ,  Kenichirou Sunata

Inventor： Hyun-Joong Kim ,  Yasushi Shioya ,  Kenichirou Sunata

IPC: B01D53/46 ,  C09K3/00

CPC classification number: B01D53/02 ,  B01D2253/108 ,  B01D2258/0216 ,  B01J20/0218 ,  B01J20/0225 ,  B01J20/0229 ,  B01J20/0237 ,  B01J20/0244 ,  B01J20/0277 ,  B01J20/06 ,  B01J20/18 ,  B01J20/3014 ,  B01J2220/42

Abstract: A detoxifying agent and a detoxifying method are provided which have a high detoxifying ability in a detoxifying treatment of a discharge gas containing a volatile inorganic hydride and generating in a semiconductor production step. A zeolite is added to a solid metal hydroxide, a solid metal carbonate, a solid basic metal carbonate, or a mixture of these compounds to thereby obtain the detoxifying agent which has the excellent ability to detoxify a discharge gas containing volatile inorganic hydride. The zeolite to be added is a synthetic zeolite selected from zeolite Y, MFI zeolite, mordenite zeolite, beta zeolite, zeolite A, zeolite X, and zeolite L or is a natural zeolite.

Abstract translation: 提供一种解毒剂和解毒方法，其在含有挥发性无机氢化物的放电气体的无毒化处理中具有高的解毒能力，并且在半导体制造步骤中产生。 向固体金属氢氧化物，固体金属碳酸盐，固体碱性金属碳酸盐或这些化合物的混合物中加入沸石，从而得到对含有挥发性无机氢化物的放电气体具有优异的解毒能力的解毒剂。 要加入的沸石是选自沸石Y，MFI沸石，丝光沸石，β沸石，沸石A，沸石X和沸石L的合成沸石，或是天然沸石。

公开(公告)号：US20110269217A1

公开(公告)日：2011-11-03

申请号：US13079466

申请日：2011-04-04

Applicant: Heesoo EUN ,  Hiroaki FUKUI

Inventor： Heesoo EUN ,  Hiroaki FUKUI

IPC: C12N1/20 ,  C01B31/08 ,  B01J29/06 ,  B01D39/00 ,  B01J20/24 ,  B01J20/02 ,  B01J20/26 ,  B09C1/08 ,  B01J20/00 ,  B01J21/16

CPC classification number: A01C21/002 ,  B01J20/043 ,  B01J20/14 ,  B01J20/18 ,  B01J20/20 ,  B01J20/26 ,  B01J20/28004 ,  B01J20/2803 ,  B01J20/28042 ,  B01J20/28057 ,  B01J20/3014 ,  B01J2220/62 ,  D21H21/18 ,  D21H21/22 ,  D21H21/52

Abstract: A hazardous substance adsorbing tablet prepared by direct compression of a dry powder mixture which includes a porous particulate adsorbent having an average particle diameter of 100 μm or less and containing 200 mesh pass particles in an amount of more than 80% by weight, and a particulate binder having an apparent specific gravity of at least 1.

Abstract translation: 通过直接压缩干粉混合物制备的有害物质吸附片剂，其包括平均粒径为100μm以下的多孔颗粒吸附剂，并且含有大于80重量％的200目筛粒子，以及颗粒 表观比重至少为1的粘合剂。

公开(公告)号：US07897037B2

公开(公告)日：2011-03-01

申请号：US11858575

申请日：2007-09-20

Applicant: Carolus Matthias Anna Maria Mesters

Inventor： Carolus Matthias Anna Maria Mesters

IPC: C10G45/04 ,  C10G45/60 ,  B01J23/00 ,  B01J21/00 ,  B01J20/00

CPC classification number: B01J20/3007 ,  B01D53/8603 ,  B01J20/0225 ,  B01J20/0244 ,  B01J20/06 ,  B01J20/08 ,  B01J20/28016 ,  B01J20/3014 ,  B01J20/3078 ,  B01J20/3204 ,  B01J20/3236 ,  B01J23/755 ,  B01J23/80 ,  B01J35/0073 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/04 ,  B01J37/16 ,  B01J37/18 ,  B01J2220/42 ,  C10G45/06 ,  C10G2300/202

Abstract: A catalyst is provided comprising nickel in a reduced valence state on a carrier comprising zinc oxide and alumina, wherein the Zn:Ni atomic ratio is at least 12, and the catalyst particles are prepared by: mixing zinc oxide in the form of a powder and alumina or an alumina precursor in the form of a powder; peptizing the powder mixture and forming an extrudable dough by adding acid and water to the powder mixture in such amounts that the dough contains 0.8-1.2 moles acid equivalents per kg powder; extruding the extrudable dough to form extrudates; drying and calcining the extrudates; impregnating the extrudates with an aqueous solution of a nickel compound; drying, calcining and reducing the impregnated extrudates. Further provided is a process for desulphurization of a hydrocarbonaceous feedstock using such catalyst.

Abstract translation: 提供一种催化剂，其包含在包含氧化锌和氧化铝的载体上的还原价态的镍，其中Zn:Ni原子比为至少12，催化剂颗粒通过以下方式制备：将粉末形式的氧化锌和 氧化铝或粉末形式的氧化铝前体; 将粉末混合物胶化并通过向粉末混合物中加入酸和水形成可挤出生面团，其量使得面团含有0.8-1.2摩尔酸当量/ kg粉末; 挤出可挤出的面团以形成挤出物; 干燥和煅烧挤出物; 用镍化合物的水溶液浸渍挤出物; 干燥，煅烧和还原浸渍的挤出物。 还提供了使用这种催化剂对含烃原料进行脱硫的方法。