摘要:
The present invention discloses chiral siliceous composition comprising chiral or achiral silane moiety ‘A’, substituted in another moiety ‘B’ with tetrahedral metallo-silica or silica framework with mesoporous and microporous structure, useful as chiral heterogeneous catalyst and in enantioselective separations. The invention further discloses a method for introducing molecular level chirality in crystalline framework of silicate and metallosilicate with mesoporous or microporous structure thereof.
摘要:
A filter for filtering particulate matter (PM) from exhaust gas emitted from a compression ignition engine, which filter comprising a porous substrate having inlet surfaces and outlet surfaces, wherein the inlet surfaces are separated from the outlet surfaces by a porous structure containing pores of a first mean pore size, wherein the porous substrate is coated with a wash coat comprising a plurality of solid particles comprising a molecular sieve promoted with at least one metal wherein the porous structure of the wash coated porous substrate contains pores of a second mean pore size, and wherein the second mean pore size is less than the first mean pore size.
摘要:
Binderless zeolite L particles are prepared by a method in which particles are formed from silica and from 0 to 95 wt % preformed zeolite L crystallites, and the particles are thereafter reacted with an alkaline solution comprising a source of alumina to convert the silica binder to zeolite L. These particles may comprise cylindrical zeolite L crystallites with a mean diameter of at least 0.05 micron in a zeolite L matrix and may be used as catalyst. Also acyclic hydrocarbons are dehydrocyclized and/or isomerized by contacting them at a temperature of from 370.degree. C. to 600.degree. C. with this catalyst incorporating at least one Group VIII metal having dehydrogenating activity to convert at least part of the acyclic hydrocarbons into aromatic hydrocarbons.
摘要:
Binderless zeolite L particles are prepared by a method in which particles are formed from silica and from 0 to 95 wt % preformed zeolite L crystallites, and the particles are thereafter reacted with an alkaline solution comprising a source of alumina to convert the silica binder to zeolite L. These particles may comprise cylindrical zeolite L crystallites with a mean diameter of at least 0.05 micron in a zeolite L matrix and may be used as catalyst. Also acyclic hydrocarbons are dehydrocyclized and/or isomerized by contacting them at a temperature of from 370.degree. C. to 600.degree. C. with this catalyst incorporating at least one Group VIII metal having dehydrogenating activity to convert at least part of the acyclic hydrocarbons into aromatic hydrocarbons.
摘要:
To develop a zeolite catalyst which can prevent the drastic lowering of dimethylamine selectivity to be caused in the production of dimethylamine using a zeolite catalyst when the conversion of methanol is high, and which can give higher dimethylamine selectivity and lower trimethylamine selectivity as well as higher methanol-consuming reaction activity; and to provide a process for producing dimethylamine with high selectivity, using the catalyst. A process for producing dimethylamine by allowing methanol, or methanol and a methylamine mixture, or a methylamine mixture to react with ammonia in the gaseous phase in the presence of a catalyst, characterized in that a modified zeolite prepared by treating a zeolite with a solution containing a chelating agent is used as the catalyst.
摘要:
Silica-bound extruded zeolites may be converted into binder-free zeolite aggregates by aging the zeolite in an aqueous ionic solution which contains hydroxy ions such that the initial molar ratio of OH.sup.- :SiO.sub.2 is up to 1.2 and which causes the silica binder to be converted substantially to zeolite of the type initially bound. Such extrudates have excellent mechanical strength and show advantageous properties such as adsorption comparable with non-extruded zeolite powder.
摘要:
The cracking catalyst of the invention contains:(a) 20-95% by weight of at least one matrix, selected from the group consisting of alumina, silica, magnesia, clay, titanium oxide, zirconia, combinations of at least two of these compounds and alumina-boron oxide combinations,(b) 1-60% by weight of at least one zeolite of open structure whose main dodecagonal channels have openings of at least 7 Angstroms, said zeolite of open structure being selected from the group formed of X, Y, L, omega and beta zeolites,(c) 0.5-60% by weight of at least one offretite whose main dodecagonal channels have openings smaller than 7 Angstroms and which have a SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio from about 15 to about 500, the crystalline parameters a and c of elementary mesh ranging respectively from 1.285 to 1.315 nm for a and from 0.748 to 0.757 nm for c and have a potassium content lower than 1.5% by weight.
摘要翻译:本发明的裂化催化剂包含:(a)20-95重量%的至少一种选自氧化铝,二氧化硅,氧化镁,粘土,氧化钛,氧化锆,这些化合物中的至少两种的组合的基质 和氧化铝 - 氧化硼组合,(b)1-60重量%的至少一种开口结构的沸石,其主要十二边形通道具有至少7埃的开口,所述开放结构的沸石选自由X, Y,L,ω和β沸石,(c)0.5-60%重量的至少一种其主要十二边形通道的开口小于7埃,并且具有约15至约500的SiO 2 / Al 2 O 3摩尔比, 基本网格的结晶参数a和c分别为1.85〜1.315nm,c为0.748〜0.757nm,钾含量低于1.5重量%。
摘要:
Zeolites washed with aqueous solutions or water or exhibit pH in the range of 9.4 to 10.0 and preferably 9.6 to 10.0 which can be converted to reforming catalysts with enhanced activity, selectivity and activity maintenance. Also processes for washing the zeolite to the target pH range and processes for using catalysts made with the washed zeolite to reform naphtha feeds.
摘要:
Molecular sieve compositions are prepared by extracting aluminum and substituting titanium and/or iron for extracted aluminum to give molecular sieve products containing framework titanium and/or iron atoms. The process of preparing the titanium and/or iron-containing molecular sieves involves contacting a starting zeolite with a solution or slurry of a fluoro salt of titanium and/or iron under effective process conditions to provide for aluminum extraction and substitution of titanium and/or iron.