Polysilane, its production process and starting materials therefor
    46.
    发明授权
    Polysilane, its production process and starting materials therefor 失效
    聚硅烷,其生产工艺及其原料

    公开(公告)号:US5830972A

    公开(公告)日:1998-11-03

    申请号:US629602

    申请日:1996-04-09

    摘要: A polysilane is disclosed whose main chain skeleton has a repeating unit represented by the general formula (1): ##STR1## wherein R.sub.1 represents a substituted or unsubstituted alkyl cycloalkyl, aryl or aralkyl group; X is a atom having an unpaired electron or a group containing an atom having an unpaired electron and represents an oxygen atom, sulfer atom or a nitrogen atom-containing group represented by the general formula (2): ##STR2## wherein R.sub.2 represents a substituted or unsubstituted alkyl, cycloalkyl, aryl or aralkyl group; Ar.sub.1 represents a substituted or unsubstituted arylene group; and Ar.sub.2 represents a substituted or unsubstituted aryl group, a group having an aromatic amine skeleton or a group ethenylene skeleton; a process for producing the polysilane; and a dihalosilane which is the starting material therefor. The polysilane compound has an excellent moldability as a high polymeric material and a higher hole drift mobility as a hole transporting material.

    摘要翻译: 公开了一种聚硅烷,其主链骨架具有由通式(1)表示的重复单元:其中R 1表示取代或未取代的烷基环烷基,芳基或芳烷基; X是具有不成对电子的原子或含有不成对电子的原子的基团,并且表示由通式(2)表示的氧原子,硫原子或含氮原子的基团:其中R2表示取代的 或未取代的烷基,环烷基,芳基或芳烷基; Ar 1表示取代或未取代的亚芳基; Ar 2表示取代或未取代的芳基,具有芳香族胺骨架或亚乙烯基团的基团; 聚硅烷的制造方法; 和作为其原料的二卤代硅烷。 聚硅烷化合物作为高分子材料具有极好的成型性,作为空穴传输材料具有较高的空穴漂移迁移率。