公开(公告)号：US20170014803A1

公开(公告)日：2017-01-19

申请号：US15225676

申请日：2016-08-01

Applicant: The Regents of The University of California

Inventor： Meera A. Sidheswaran ,  Hugo Destaillats ,  William J. Fisk

IPC: B01J23/34 ,  B01J35/02 ,  B01D53/86 ,  B01J37/08 ,  B01J35/04 ,  C09D7/12 ,  B01J35/10 ,  B01J37/03

CPC classification number: B01J23/34 ,  A61L9/00 ,  B01D53/8668 ,  B01D2253/102 ,  B01D2255/2073 ,  B01D2257/106 ,  B01D2257/708 ,  B01J20/20 ,  B01J21/18 ,  B01J35/002 ,  B01J35/006 ,  B01J35/023 ,  B01J35/04 ,  B01J35/06 ,  B01J35/1009 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1028 ,  B01J37/0215 ,  B01J37/031 ,  B01J37/08 ,  C09D1/00 ,  C09D7/61 ,  Y02A50/235

Abstract: The present invention provides for a device for reducing a volatile organic compound (VOC) content of a gas comprising a manganese oxide (MnOx) catalyst. The manganese oxide (MnOx) catalyst is capable of catalyzing formaldehyde at room temperature, with complete conversion, to CO2 and water vapor. The manganese oxide (MnOx) catalyst itself is not consumed by the reaction of formaldehyde into CO2 and water vapor. The present invention also provides for a device for reducing or removing a particle, a VOC and/or ozone from a gas comprising an activated carbon filter (ACF) on a media that is capable of being periodically regenerated.

Abstract translation: 本发明提供一种用于还原包含氧化锰（MnO x）催化剂的气体的挥发性有机化合物（VOC）含量的装置。 氧化锰（MnOx）催化剂能够在室温下完全催化甲醛，完全转化为二氧化碳和水蒸气。 氧化锰（MnOx）催化剂本身不会被甲醛与二氧化碳和水蒸气的反应所消耗。 本发明还提供了一种用于在能够周期性再生的介质上从包含活性炭过滤器（ACF）的气体中还原或除去颗粒，VOC和/或臭氧的装置。

公开(公告)号：US20160318009A1

公开(公告)日：2016-11-03

申请号：US15102287

申请日：2013-12-11

Applicant: DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES

Inventor： Yunjie DING ,  Miao JIANG ,  Li YAN ,  Ronghe LIN

IPC: B01J31/24 ,  C07C45/50 ,  B01J37/08 ,  C08J9/28 ,  B01J35/10 ,  B01J37/04

CPC classification number: B01J31/24 ,  B01J23/464 ,  B01J23/468 ,  B01J23/75 ,  B01J31/00 ,  B01J31/165 ,  B01J31/2404 ,  B01J35/065 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1028 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1057 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/04 ,  B01J37/08 ,  B01J2231/321 ,  B01J2531/822 ,  B01J2531/827 ,  B01J2531/845 ,  C07C45/50 ,  C07C45/505 ,  C08J9/286 ,  C08J2201/05 ,  C08J2205/042 ,  C08J2205/044 ,  C08J2207/00 ,  C08J2343/02 ,  C07C47/02

Abstract: A solid heterogeneous catalyst consisting of a metal component and an organic ligand polymer, wherein the metal component is one or more of Rh, Ir or Co, the organic ligand polymer is a polymer having a large specific surface area and hierarchical porosity formed by polymerizing an organic ligand monomer containing P and alkenyl group and optional N via a solvothermal polymerization process, the metal component forms coordinated bond with the P atom or N in backbone of the organic ligand polymer and exists in a monoatomic dispersion state; when the catalyst is used in an olefin hydroformylation reaction, the metal component and the P and/or N atom form in situ an intermediate active species similar to homogeneous catalyst due to the coordination effect, and the catalyst has an excellent catalytic property, can be easily separated, and has a relatively high stability.

Abstract translation: 一种由金属组分和有机配体聚合物组成的固体多相催化剂，其中金属组分是Rh，Ir或Co中的一种或多种，​​有机配体聚合物是具有大比表面积的聚合物和通过聚合形成的分级孔隙率 含有P和烯基的有机配体单体和任选的N通过溶剂热聚合方法，金属组分与有机配体聚合物的主链中的P原子或N形成配位键，并以单原子分散状态存在; 当催化剂用于烯烃加氢甲酰化反应时，由于配位作用，金属组分和P和/或N原子原位形成类似于均相催化剂的中间活性物质，催化剂具有优异的催化性能，可以是 容易分离，并具有较高的稳定性。

公开(公告)号：US09468922B1

公开(公告)日：2016-10-18

申请号：US14737085

申请日：2015-06-11

Applicant: Paul A. Goodman

Inventor： Paul A. Goodman

IPC: B01J37/08 ,  B01J23/42 ,  B01J23/44 ,  B01J23/52 ,  B01J21/18 ,  B01J35/00 ,  B01J35/10 ,  B01J37/03

CPC classification number: B01J37/084 ,  B01J21/18 ,  B01J23/42 ,  B01J23/44 ,  B01J23/52 ,  B01J27/1856 ,  B01J35/0013 ,  B01J35/026 ,  B01J35/1023 ,  B01J35/1028 ,  B01J37/0201 ,  B01J37/035 ,  B01J37/06 ,  B01J37/16

Abstract: Pyrolysis of machined osseous tissue results in a monolith of carbon interwoven within the HA scaffold native to the original tissue. This HA framework prevents the collapse of the carbon to dense forms during pyrolysis. Upon removal of the HA scaffold after pyrolysis, a monolith that preserves the macroscopic form of the carbon remains. The monolith is placed in a solution of catalyst, noble metal ions for example, which is then reduced to facilitate the precipitation of nanoparticles of the catalyst. The novelty of this invention is that a high number of particles are contained within a relatively small, extremely high surface area solid support. The current invention demonstrates that the pyrolysis of intact bovine cortical bone produces high-carbon-surface-area monoliths, which can be used as a scaffold for reusable catalysts.

Abstract translation: 加工的骨组织的热解导致在原始组织天然的HA支架内交织的整体碳。 该HA框架防止在热解过程中碳到致密形式的崩溃。 在热解后除去HA支架后，保留了保留宏观形式的碳的整料。 将整料置于例如催化剂，贵金属离子的溶液中，然后将其还原以促进催化剂纳米颗粒的沉淀。 本发明的新颖之处在于，在相对小的极高表面积的固体支持物中含有大量的颗粒。 本发明表明，完整牛皮质骨的热解产生高碳表面积整料，可用作可重复使用的催化剂的支架。

公开(公告)号：US20160296911A1

公开(公告)日：2016-10-13

申请号：US15103065

申请日：2014-11-25

Applicant: BLÜCHER GMBH ,  FRIEDRICH ALEXANDER UNIVERSITÄT ERLANGEN-NÜRNBERG

Inventor： Bertram Bohringer ,  Sven Fichtner ,  Christian Schrage ,  Jann-Michael Giebelhausen ,  Peter Wasserscheldt ,  Bastian Etzold ,  Heiko Klefer

IPC: B01J23/46 ,  B01J35/00 ,  B01J35/08 ,  B01J35/10 ,  H01M4/90 ,  B01J37/02 ,  B01J37/16 ,  A62D5/00 ,  B01D39/20 ,  B01J21/18 ,  B01J37/12

CPC classification number: B01J23/462 ,  A62D5/00 ,  A62D9/00 ,  B01D39/2058 ,  B01J20/0225 ,  B01J20/20 ,  B01J20/28019 ,  B01J20/28076 ,  B01J20/3078 ,  B01J20/3085 ,  B01J20/3204 ,  B01J20/3236 ,  B01J20/3293 ,  B01J21/18 ,  B01J23/16 ,  B01J23/40 ,  B01J23/42 ,  B01J23/44 ,  B01J23/48 ,  B01J23/70 ,  B01J35/0006 ,  B01J35/0026 ,  B01J35/0093 ,  B01J35/023 ,  B01J35/08 ,  B01J35/10 ,  B01J35/1023 ,  B01J35/1028 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0207 ,  B01J37/0221 ,  B01J37/12 ,  B01J37/16 ,  B01J37/18 ,  C01B32/354 ,  C07C29/141 ,  C07C51/36 ,  C07C57/30 ,  H01M4/9083

Abstract: The invention relates to a method for producing a catalyst system having at least one catalytically active component, wherein the catalytically active component comprises at least one metal, wherein first a spherical activated carbon used as a catalyst carrier is subjected to an oxidation. Subsequently, the catalytically active component is applied, optionally followed by a reduction of the catalyst system obtained in said manner.

Abstract translation: 本发明涉及一种制备具有至少一种催化活性组分的催化剂体系的方法，其中催化活性组分包含至少一种金属，其中首先将用作催化剂载体的球形活性炭进行氧化。 随后，施加催化活性组分，任选地随后还原以所述方式获得的催化剂体系。

公开(公告)号：US20160271593A1

公开(公告)日：2016-09-22

申请号：US15168802

申请日：2016-05-31

Applicant: Saudi Basic Industries Corporation

Inventor： Khalid Karim ,  Graham Hutchings ,  Sarwat Iqbal

IPC: B01J23/887 ,  B01J35/10 ,  B01J35/00 ,  B01J23/882 ,  B01J21/18

CPC classification number: B01J23/8872 ,  B01J21/18 ,  B01J23/882 ,  B01J35/0006 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1028 ,  B01J37/035 ,  B01J37/18 ,  C07C29/156 ,  C10G2300/4018 ,  Y02P20/52 ,  C07C31/02

Abstract: The present invention relates to a catalyst composition comprising cobalt molybdenum and optionally one or more elements selected from the group consisting of alkali metals and alkaline earth metals on a carbon support wherein said cobalt and molybdenum are in their metallic form. It was surprisingly found that the selectivity for alcohols can be increased by using the carbon supported cobalt molybdenum catalyst as described herein in a process for producing alcohols from a feed stream comprising hydrogen and carbon monoxide. Furthermore, it was found that the catalyst of the present invention has a decreased selectivity for CO2 and can be operated at relatively low temperature when compared to conventional catalysts. Moreover, a method for preparing the carbon supported cobalt molybdenum catalyst composition and a process for producing alcohols using said carbon supported cobalt molybdenum catalyst composition is provided.

Abstract translation: 本发明涉及包含钴钼和任选的一种或多种选自碳载体上的碱金属和碱土金属的元素的催化剂组合物，其中所述钴和钼是其金属形式。 令人惊奇地发现，通过使用如本文所述的碳负载的钴钼催化剂在由包含氢气和一氧化碳的进料流生产醇的方法中可以提高醇的选择性。 此外，发现本发明的催化剂对CO 2的选择性降低，并且与常规催化剂相比可以在相对低的温度下操作。 此外，提供了使用所述碳负载的钴钼催化剂组合物制备碳负载的钴钼催化剂组合物的方法和制备醇的方法。

公开(公告)号：US20160233520A1

公开(公告)日：2016-08-11

申请号：US15025354

申请日：2014-09-09

Applicant: NISSAN MOTOR CO., LTD.

Inventor： Shinichi TAKAHASHI ,  Atsushi OHMA ,  Tetsuya MASHIO ,  Ken AKIZUKI

IPC: H01M4/92 ,  H01M8/1004

CPC classification number: H01M4/926 ,  B01J21/18 ,  B01J23/40 ,  B01J35/0033 ,  B01J35/1028 ,  B01J35/1042 ,  B01J35/1057 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/08 ,  C01B32/00 ,  C01P2006/12 ,  H01M4/8673 ,  H01M4/9083 ,  H01M8/1004 ,  H01M2008/1095

Abstract: The present invention is to provide a carbon powder that can provide a catalyst having excellent durability and a catalyst. A carbon powder for catalyst of the present invention is a carbon powder containing as a main component carbon, which has a BET specific surface area per unit weight of 900 m2/g or greater, and a ratio R′ (D′/G intensity ratio) of peak intensity for a D′-band (D′ intensity) measured in the vicinity of 1620 cm−1 to peak intensity for a G-band (G intensity) measured in the vicinity of 1580 cm−1 by Raman spectroscopy of 0.6 or less.

Abstract translation: 本发明提供能够提供耐久性优异的催化剂和催化剂的碳粉末。 本发明的催化剂用碳粉是以每单位面积重量比为900m 2 / g以上的比表面积和比例R'（D'/ G强度比）作为主成分碳的碳粉末 ）在1620cm -1附近测量的峰强度（D'强度）与通过拉曼光谱法测量的在1580cm -1附近的G带（G强度）的峰值强度（G强度）为0.6 或更少。

公开(公告)号：US20160175827A1

公开(公告)日：2016-06-23

申请号：US14585718

申请日：2014-12-30

Applicant: NORTHWESTERN UNIVERSITY

Inventor： Joseph T. HUPP ,  Omar K. FARHA ,  Michael J. KATZ ,  Joseph E. MONDLOCH

IPC: B01J31/16 ,  A62B7/10 ,  C07F7/00 ,  A62D3/35 ,  B01J35/10 ,  B01J35/02

CPC classification number: B01J31/1691 ,  A62B7/10 ,  A62B18/02 ,  A62B19/00 ,  A62D3/35 ,  A62D9/00 ,  A62D2101/02 ,  B01D53/04 ,  B01D2253/204 ,  B01D2253/306 ,  B01D2253/308 ,  B01D2257/408 ,  B01D2259/4583 ,  B01J20/226 ,  B01J35/023 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1028 ,  B01J35/1057 ,  B01J35/1061 ,  B01J2531/46 ,  B01J2531/48 ,  B01J2531/49 ,  C07F7/003

Abstract: A method of using a metal organic framework (MOF) comprising a metal ion and an at least bidendate organic ligand to catalytically detoxify chemical warfare nerve agents including exposing the metal-organic-framework (MOF) to the chemical warfare nerve agent and catalytically decomposing the nerve agent with the MOF.

Abstract translation: 一种使用包含金属离子和至少贱金属有机配体的金属有机骨架（MOF）的方法来催化解毒化学战神经剂，包括将金属 - 有机骨架（MOF）暴露于化学战神经剂并催化分解 神经毒素与MOF。

公开(公告)号：US20160168485A1

公开(公告)日：2016-06-16

申请号：US14966445

申请日：2015-12-11

Applicant: Quanchang LI ,  Dhaval Ajit BHANDARI ,  Benjamin A. McCOOL

Inventor： Quanchang LI ,  Dhaval Ajit BHANDARI ,  Benjamin A. McCOOL

IPC: C10G31/09 ,  B01D67/00 ,  B01D69/10 ,  C23C16/56 ,  B01D71/70

CPC classification number: B01J20/262 ,  B01D15/00 ,  B01D53/02 ,  B01D53/0462 ,  B01D53/047 ,  B01D53/228 ,  B01D67/0088 ,  B01D69/10 ,  B01D71/70 ,  B01D2253/20 ,  B01D2253/25 ,  B01D2256/245 ,  B01D2257/302 ,  B01D2257/304 ,  B01D2257/40 ,  B01D2257/504 ,  B01D2257/80 ,  B01J20/0229 ,  B01J20/0237 ,  B01J20/06 ,  B01J20/08 ,  B01J20/10 ,  B01J20/103 ,  B01J20/16 ,  B01J20/18 ,  B01J20/22 ,  B01J20/264 ,  B01J20/28011 ,  B01J20/28057 ,  B01J20/28061 ,  B01J20/28064 ,  B01J20/28066 ,  B01J20/28069 ,  B01J20/28071 ,  B01J20/28073 ,  B01J20/28076 ,  B01J20/28078 ,  B01J20/28083 ,  B01J20/286 ,  B01J20/3042 ,  B01J20/3204 ,  B01J20/3212 ,  B01J20/3236 ,  B01J20/3238 ,  B01J20/3272 ,  B01J23/42 ,  B01J23/44 ,  B01J31/0274 ,  B01J31/125 ,  B01J31/127 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1028 ,  B01J35/1061 ,  B01J37/0213 ,  B01J37/0236 ,  B01J37/036 ,  B01J2220/86 ,  B01J2231/641 ,  B01J2231/646 ,  C01B37/00 ,  C07F7/0807 ,  C07F7/081 ,  C07F7/0818 ,  C08G77/26 ,  C08G77/60 ,  C10G25/003 ,  C10G31/09 ,  C10G35/06 ,  C10G45/00 ,  C10G45/04 ,  C10G45/34 ,  C10G45/44 ,  C10G45/46 ,  C10G45/52 ,  C10G45/60 ,  C10G45/64 ,  C10G47/02 ,  C10G50/00 ,  C10K1/32 ,  C10M101/02 ,  C23C16/56

Abstract: Methods for fabricating a membrane with an organosilica material which is a polymer comprising independent units of Formula [Z3Z4SiCH2]3 (I), wherein each Z3 represents a hydroxyl group, a C1-C4 alkoxy group or an oxygen atom bonded to a silicon atom of another unit or an active site on the support and each Z4 represents a hydroxyl group, a C1-C4 alkoxy group, a C1-C4 alkyl group, an oxygen atom bonded to a silicon atom of another unit or an active site on the support are provided. Methods of removing a contaminant from a hydrocarbon stream are also provided.

Abstract translation: 制备具有有机二氧化硅材料的膜的方法，该有机硅材料是包含式[Z 3 Z 4 SiCH 2] 3（I）的独立单元的聚合物，其中Z 3表示羟基，C 1 -C 4烷氧基或与硅原子键合的氧原子 载体上的另一单元或活性位点，每个Z 4表示羟基，C 1 -C 4烷氧基，C 1 -C 4烷基，与另一单元的硅原子键合的氧原子或载体上的活性位点是 提供。 还提供了从烃流中除去污染物的方法。

公开(公告)号：US20160166988A1

公开(公告)日：2016-06-16

申请号：US14970017

申请日：2015-12-15

Applicant: RHODIA OPERATIONS ,  MAGNESIUM ELEKTRON LIMITED

Inventor： Olivier LARCHER ,  Emmanuel ROHART ,  Stephan VERDIER ,  Heather BRADSHAW ,  Clive BUTLER ,  Deborah HARRIS ,  Mairead FEELEY ,  Guillaume CRINIERE

IPC: B01D53/94 ,  B01J21/08 ,  B01J23/888 ,  B01J23/10 ,  B01J23/34 ,  B01J23/30 ,  B01J21/12

CPC classification number: B01D53/944 ,  B01D53/9418 ,  B01D53/945 ,  B01D2251/2062 ,  B01D2251/2067 ,  B01D2255/1021 ,  B01D2255/2061 ,  B01D2255/2063 ,  B01D2255/2065 ,  B01D2255/20707 ,  B01D2255/20715 ,  B01D2255/2073 ,  B01D2255/20738 ,  B01D2255/20769 ,  B01D2255/20776 ,  B01D2255/20792 ,  B01D2255/2092 ,  B01D2255/2094 ,  B01D2255/30 ,  B01D2257/404 ,  B01D2258/012 ,  B01D2259/4566 ,  B01J21/063 ,  B01J21/066 ,  B01J21/08 ,  B01J21/12 ,  B01J23/002 ,  B01J23/06 ,  B01J23/10 ,  B01J23/14 ,  B01J23/28 ,  B01J23/30 ,  B01J23/34 ,  B01J23/60 ,  B01J23/626 ,  B01J23/63 ,  B01J23/652 ,  B01J23/6562 ,  B01J23/745 ,  B01J23/888 ,  B01J23/894 ,  B01J23/8993 ,  B01J35/002 ,  B01J35/10 ,  B01J35/1023 ,  B01J35/1028 ,  B01J37/0248 ,  B01J37/03 ,  B01J2523/00 ,  C01B13/363 ,  C01G39/006 ,  C01G41/006 ,  C01G45/006 ,  C01G49/009 ,  C01P2006/12 ,  C01P2006/13 ,  Y02T10/22 ,  Y02T10/24 ,  B01J2523/31 ,  B01J2523/41 ,  B01J2523/48 ,  B01J2523/36 ,  B01J2523/69 ,  B01J2523/72 ,  B01J2523/842 ,  B01J2523/47 ,  B01J2523/3712 ,  B01J2523/27 ,  B01J2523/43

Abstract: Compositions useful for treating the exhaust gases of diesel engines contain zirconium oxide, silicon oxide and at least one oxide of at least one element M selected from among titanium, aluminum, tungsten, molybdenum, cerium, iron, tin, zinc, and manganese, in the following mass proportions of these different elements: silicon oxide: 5%-30%; M-element oxide: 1%-20%; the balance being zirconium oxide; such compositions also have an acidity, as measured by the methylbutynol test, of at least 90% and are prepared by placing a zirconium compound, a silicon compound, at least one M-element compound and a basic compound in a liquid medium, thereby generating a precipitate, maturing the precipitate in a liquid medium and separating and calcining the precipitate.

Abstract translation: 用于处理柴油发动机废气的组合物含有氧化锆，氧化硅和选自钛，铝，钨，钼，铈，铁，锡，锌和锰中的至少一种元素M的至少一种氧化物， 这些不同元素的以下质量比例：氧化硅：5％-30％; M元素氧化物：1％-20％; 余量为氧化锆; 这种组合物还具有至少90％的通过甲基丁炔测试测得的酸度，并且通过在液体介质中放置锆化合物，硅化合物，至少一种M元素化合物和碱性化合物来制备，由此产生 沉淀物，使沉淀物在液体介质中成熟并分离和煅烧沉淀物。

公开(公告)号：US20160136702A1

公开(公告)日：2016-05-19

申请号：US15006294

申请日：2016-01-26

Applicant: REMEDIATION PRODUCTS, INC.

Inventor： SCOTT NOLAND ,  BOB ELLIOTT

IPC: B09C1/08 ,  C02F1/28 ,  B09C1/10 ,  B01J20/20 ,  B09C1/00

CPC classification number: C02F1/58 ,  B01J20/02 ,  B01J20/20 ,  B01J20/28057 ,  B01J20/28064 ,  B01J20/28066 ,  B01J20/3078 ,  B01J20/3204 ,  B01J20/3236 ,  B01J21/18 ,  B01J23/745 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1028 ,  B01J37/082 ,  B01J37/088 ,  B01J37/16 ,  B09C1/002 ,  B09C1/08 ,  B09C1/10 ,  B09C2101/00 ,  C02F1/281 ,  C02F1/283 ,  C02F1/288 ,  C02F1/705 ,  C02F3/104 ,  C02F3/2806 ,  C02F3/34 ,  C02F2101/101 ,  C02F2101/32 ,  C02F2101/36 ,  C02F2103/06 ,  C02F2305/06 ,  C09K17/02 ,  Y02E50/343 ,  Y02W10/15 ,  Y10T428/12181

Abstract: A composition for in situ remediation of soil and groundwater contaminated with hydrocarbons. The composition includes an adsorbent, such as activated carbon, capable of adsorbing the hydrocarbons. The composition also includes a sulfate-containing compound that releases sulfate over a period of time, e.g., a time-release compound that may include calcium sulfate. The composition includes a nutrient system for promoting growth of facultative anaerobes, in the soil or provided in the composition itself. In some embodiments, the nutrient system includes a sulfide scavenging agent such as iron sulfate. In the same or other embodiments, the nutrient system includes at least one of a nitrogen source and a phosphorous source.

Abstract translation: 用于碳氢化合物污染的土壤和地下水的原位修复组合物。 组合物包括能够吸附烃的吸附剂，例如活性炭。 该组合物还包括在一段时间内释放硫酸盐的硫酸盐化合物，例如可包括硫酸钙的时间释放化合物。 该组合物包括用于促进兼性厌氧菌在土壤中或在组合物本身中提供的营养体系。 在一些实施方案中，营养系统包括硫化物清除剂，例如硫酸铁。 在相同或其它实施方案中，营养体系包括氮源和磷源中的至少一种。