Method for capping copper in semiconductor devices
    1.
    发明授权
    Method for capping copper in semiconductor devices 失效
    在半导体器件中封装铜的方法

    公开(公告)号:US5447887A

    公开(公告)日:1995-09-05

    申请号:US222759

    申请日:1994-04-01

    摘要: A silicon nitride layer (34) has improved adhesion to underlying copper interconnect members (30) through the incorporation of an intervening copper silicide layer (32). Layer (32) is formed in-situ with a plasma enhanced chemical vapor deposition (PECVD) process for depositing silicon nitride layer (34). To form layer (32), a semiconductor substrate (12) is provided having a desired copper pattern formed thereon. The copper pattern may include copper interconnects, copper plugs, or other copper members. The substrate is placed into a PECVD reaction chamber. Silane is introduced into the reaction chamber in the absence of a plasma to form a copper silicide layer on any exposed copper surfaces. After a silicide layer of a sufficient thickness (for example, 10 to 100 angstroms) is formed, PECVD silicon nitride is deposited. The copper silicide layer improves adhesion, such that silicon nitride layer is less prone to peeling away from underlying copper members.

    摘要翻译: 氮化硅层(34)通过引入中间铜硅化物层(32)而具有改进的对底层铜互连构件(30)的粘合性。 用等离子体增强化学气相沉积(PECVD)工艺原位形成层(32),用于沉积氮化硅层(34)。 为了形成层(32),提供了在其上形成有所需铜图案的半导体衬底(12)。 铜图案可以包括铜互连,铜插头或其它铜构件。 将基板放入PECVD反应室中。 在不存在等离子体的情况下将硅烷引入反应室,以在任何暴露的铜表面上形成硅化铜层。 在形成足够厚度(例如10至100埃)的硅化物层之后,沉积PECVD氮化硅。 硅化铜层提高粘合性,使得氮化硅层不容易从下面的铜构件剥离。

    Electroless deposition process on a silicide contact
    3.
    发明申请
    Electroless deposition process on a silicide contact 审中-公开
    硅化物接触时的无电沉积工艺

    公开(公告)号:US20060246217A1

    公开(公告)日:2006-11-02

    申请号:US11385047

    申请日:2006-03-20

    IPC分类号: B28B19/00 C23C18/34

    摘要: Embodiments as described herein provide methods for depositing a material on a substrate during electroless deposition processes, as well as compositions of the electroless deposition solutions. In one embodiment, the substrate contains a contact aperture having an exposed silicon contact surface. In another embodiment, the substrate contains a contact aperture having an exposed silicide contact surface. The apertures are filled with a metal contact material by exposing the substrate to an electroless deposition process. The metal contact material may contain a cobalt material, a nickel material, or alloys thereof. Prior to filling the apertures, the substrate may be exposed to a variety of pretreatment processes, such as preclean processes and activations processes. A preclean process may remove organic residues, native oxides, and other contaminants during a wet clean process or a plasma etch process. Embodiments of the process also provide the deposition of additional layers, such as a capping layer.

    摘要翻译: 本文所述的实施方案提供了在无电沉积工艺期间在基材上沉积材料的方法以及无电沉积溶液的组合物。 在一个实施例中,衬底包含具有暴露的硅接触表面的接触孔。 在另一个实施例中,衬底包含具有暴露的硅化物接触表面的接触孔。 通过将基板暴露于无电镀沉积工艺,用金属接触材料填充孔。 金属接触材料可以包含钴材料,镍材料或其合金。 在填充孔之前,衬底可以暴露于各种预处理工艺,例如预清洗工艺和激活工艺。 预清洗方法可以在湿式清洁工艺或等离子体蚀刻工艺期间去除有机残余物,天然氧化物和其它污染物。 该方法的实施方案还提供附加层的沉积,例如覆盖层。

    METHODS FOR ANNEALING A METAL CONTACT LAYER TO FORM A METAL SILICIDATION LAYER
    8.
    发明申请
    METHODS FOR ANNEALING A METAL CONTACT LAYER TO FORM A METAL SILICIDATION LAYER 有权
    用于退火金属接触层以形成金属硅酸盐层的方法

    公开(公告)号:US20130157460A1

    公开(公告)日:2013-06-20

    申请号:US13714588

    申请日:2012-12-14

    IPC分类号: H01L29/40

    CPC分类号: H01L29/401 H01L21/28052

    摘要: Methods for annealing a contact metal layer for a metal silicidation process are provided in the present invention. In one embodiment, a method for annealing a contact metal layer for a silicidation process in a semiconductor device includes providing a substrate having a contact metal layer disposed thereon in a thermal annealing processing chamber, providing a heat energy to the contact metal layer in the thermal processing chamber, supplying a gas mixture including a nitrogen gas and a hydrogen gas while providing the heat energy to the contact layer in the thermal processing chamber, wherein the nitrogen gas and the hydrogen gas is supplied at a ratio between about 1:10 and about 1:1, and forming a metal silicide layer on the substrate.

    摘要翻译: 在本发明中提供了用于退火金属硅化工艺的接触金属层的方法。 在一个实施例中,一种用于对半导体器件中的硅化工艺的接触金属层进行退火的方法包括:在热退火处理室中提供其上设置有接触金属层的基板,在该热退火处理室中向该接触金属层提供热能 处理室,供给包括氮气和氢气的气体混合物,同时向热处理室中的接触层提供热能,其中氮气和氢气以约1:10和约 1:1,并在衬底上形成金属硅化物层。