Method for producing bis(aminomethyl)cyclohexanes
    10.
    发明授权
    Method for producing bis(aminomethyl)cyclohexanes 有权
    双(氨基甲基)环己烷的制备方法

    公开(公告)号:US08865938B2

    公开(公告)日:2014-10-21

    申请号:US13877595

    申请日:2011-10-05

    摘要: A method for producing bis(aminomethyl)cyclohexanes includes a nuclear hydrogenation step of producing hydrogenated phthalic acids or phthalic acid derivatives by nuclear hydrogenation of phthalic acids or phthalic acid derivatives of at least one selected from the group consisting of phthalic acids, phthalic acid esters, and phthalic acid amides; a cyanation step of treating the hydrogenated phthalic acids or phthalic acid derivatives obtained in the nuclear hydrogenation step with ammonia, thereby producing dicyanocyclohexanes; and an aminomethylation step of treating the dicyanocyclohexanes obtained in the cyanation step with hydrogen, thereby producing bis(aminomethyl)cyclohexanes. In the cyanation step, metal oxide is used as a catalyst, and the obtained dicyanocyclohexanes have a metal content of 3000 ppm or less.

    摘要翻译: 制备双(氨基甲基)环己烷的方法包括核氢化步骤,其通过邻苯二甲酸或邻苯二甲酸衍生物的核氢化制备氢化邻苯二甲酸或邻苯二甲酸衍生物,所述邻苯二甲酸或邻苯二甲酸衍生物选自邻苯二甲酸,邻苯二甲酸酯, 和邻苯二甲酸酰胺; 氰化步骤,用氨处理在核氢化步骤中得到的氢化邻苯二甲酸或邻苯二甲酸衍生物,从而产生二氰基环己烷; 和在氰化步骤中用氢处理二氰基环己烷的氨基甲基化步骤,从而产生双(氨基甲基)环己烷。 在氰化步骤中,使用金属氧化物作为催化剂,所得到的二氰基环己烷的金属含量为3000ppm以下。