ENHANCEMENT OF THERMOELECTRIC PROPERTIES THROUGH POLARIZATION ENGINEERING
    19.
    发明申请
    ENHANCEMENT OF THERMOELECTRIC PROPERTIES THROUGH POLARIZATION ENGINEERING 审中-公开
    通过极化工程提高热电性能

    公开(公告)号:US20140318592A1

    公开(公告)日:2014-10-30

    申请号:US14367087

    申请日:2012-12-14

    CPC classification number: H01L35/22 C30B23/066 C30B25/02 H01L35/26 H01L35/34

    Abstract: A method for enhancement of thermoelectric properties through polarization engineering. Internal electric fields created within a material are used to spatially confine electrons for the purpose of enhancing thermoelectric properties. Electric fields can be induced within a material by the presence of bound charges at interfaces. A combination of spontaneous and piezoelectric polarization can induce this interfacial charge. The fields created by these bound charges have the effect of confining charge carriers near these interfaces. By confining charge carriers to a channel where scattering centers can be deliberately excluded the electron mobility can be enhanced, thus enhancing thermoelectric power factor. Simultaneously, phonons will not be affected by the fields and thus will be subject to the many scattering centers present in the majority of the structure. This allows for simultaneous enhancement of power factor and reduction of thermal conductivity, thus improving the thermoelectric figure of merit, ZT. This approach is also compatible with other strategies for reducing thermal conductivity, for example the inclusion of nanostructures.

    Abstract translation: 通过极化工程增强热电性能的方法。 在材料内产生的内部电场用于空间上限制电子,以增强热电性能。 通过在界面处存在结合的电荷,可以在材料内诱导电场。 自发和压电极化的组合可以引起这种界面电荷。 由这些绑定的电荷产生的磁场具有限制这些接口附近的电荷载体的作用。 通过将电荷载流子限制在可以有意排除散射中心的通道,可以增强电子迁移率,从而提高热电功率因数。 同时,声子不会受到这些领域的影响,因此将受到大多数结构中存在的许多散射中心的制约。 这允许同时增强功率因数和降低热导率,从而提高热电特性值ZT。 这种方法也适用于降低导热性的其他策略,例如纳入纳米结构。

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