Abstract:
A functional structural body includes a skeletal body of a porous structure composed of a zeolite-type compound, and at least one type of metallic nanoparticles present in the skeletal body, the skeletal body having channels connecting with each other, the metallic nanoparticles being present at least in the channels of the skeletal body.
Abstract:
The present disclosure provides a method for preparing a molecular sieve catalyst. A water-in-oil micro-emulsion including a continuous phase containing an organic solvent and a dispersed phase containing an aqueous solution containing one or more metal salts and a water-soluble organic carbon source is prepared, hydrolyzed, and azeotropically distilled to form a mixture solution. The mixture solution is heated to carbonize the water-soluble organic carbon source to form nanoparticles each having a core-shell structure including a carbon-shelled metal-oxide. The nanoparticles containing the carbon-shelled metal-oxide are dispersed in a molecular sieve precursor solution. A nanoparticle-loaded molecular sieve is formed from the molecular sieve precursor solution containing the nanoparticles, and then calcined to remove carbon there-from to form a metal-oxide loaded molecular sieve.
Abstract:
A hydrocarbon trap is provided for reducing cold-start hydrocarbon emissions. The trap comprises a monolithic flow-through substrate having a porosity of at least 60% and including a zeolite loading of at least 4 g/in3 in or on its walls. A separate coating of a three-way catalyst is provided over the zeolite coating. The trap may further include an oxygen storage material. The hydrocarbon trap may be positioned in the exhaust gas system of a vehicle such that unburnt hydrocarbons are adsorbed on the trap and stored until the monolith reaches a sufficient temperature for catalyst activation.
Abstract translation:提供了一种用于减少冷启动碳氢化合物排放的烃阱。 捕集器包括具有至少60%的孔隙度并且包括在其壁中或其壁上的至少4g / in 3的沸石负载的单片流通基材。 在沸石涂层上提供单独的三元催化剂涂层。 捕集器还可以包括储氧材料。 碳氢化合物阱可以定位在车辆的排气系统中,使得未燃烧的烃被吸附在捕集器上并储存,直到整料达到足够的催化剂活化温度。
Abstract:
An alkylation catalyst having a zeolite catalyst component and a binder component providing mechanical support for the zeolite catalyst component is disclosed. The binder component is an ion-modified binder that can include metal ions selected from the group consisting of Co, Mn, Ti, Zr, V, Nb, K, Cs, Ga, B, P, Rb, Ag, Na, Cu, Mg, Fe, Mo, Ce, and combinations thereof The metal ions reduce the number of acid sites on the zeolite catalyst component. The metal ions can range from 0.1 to 50 wt % based on the total weight of the ion-modified binder. Optionally, the ion-modified binder is present in amounts ranging from 1 to 80 wt % based on the total weight of the catalyst.
Abstract:
The crystal size and shape of zeolite KL can be improved by forming the zeolite from a synthesis mixture in which the molar ratio of K.sub.2 O/SiO.sub.2 is 0.18 to 0.36, and in which the synthesis mixture comprises iron preferably in an amount such that the molar ratio of Fe.sub.2 O.sub.3 /Al.sub.2 O.sub.3 is 0.015 to 0.3.
Abstract translation:PCT No.PCT / EP92 / 00246 Sec。 371日期:1993年10月25日 102(e)日期1993年10月25日PCT提交1992年2月4日PCT公布。 第WO92 / 13799号公报 1992年8月20日。沸石KL的晶体尺寸和形状可以通过从其中K 2 O / SiO 2的摩尔比为0.18至0.36的合成混合物形成沸石而得到改善,其中合成混合物包含铁,优选在 使Fe 2 O 3 / Al 2 O 3的摩尔比为0.015〜0.3的量。
Abstract:
The process of the invention comprises oxidizing and then sulfiding materials comprising Group VIA or Group VIIIA (first or second row) catalytic metal on a nonacidic porous support, to produce compositions which have good dispersion of a catalytically active metal component and of sulfide species over the surface of the compositions and high activity as catalysts for the dehydrogenation of organic compounds.
Abstract:
Disclosed is a method of preparing a high-performance zeolite catalyst for reducing nitrogen oxide emissions, and more particularly a technique for preparing a zeolite catalyst, suitable for use in effectively removing nitrogen oxide (NOx), among exhaust gases emitted from vehicle internal combustion engines through selective catalytic reduction (SCR), thereby exhibiting high efficiency, high chemical stability and high thermal durability upon SCR using the prepared catalyst.
Abstract:
A functional structural body that can realize a prolonged life time by suppressing the decrease in function and that can fulfill resource saving without requiring a complicated replacement operation is provided. A functional structural body includes a skeletal body of a porous structure composed of a zeolite-type compound; and at least one solid acid present in the skeletal body, the skeletal body has channels connecting with each other, and the solid acid is present at least in the channels of the skeletal body.
Abstract:
Disclosed is a process and system to convert acyclic C5 feedstock to non-aromatic, cyclic C5 hydrocarbon. A furnace and reactor tubes comprising a catalyst compound are disclosed. A process involving contacting acyclic C5 feedstock with catalyst composition and obtaining cyclic C5 hydrocarbon is also disclosed.
Abstract:
A hydrocarbon trap is provided for reducing cold-start hydrocarbon emissions. The trap comprises a monolithic flow-through substrate having a porosity of at least 60% and including a zeolite loading of at least 4 g/in3 in or on its walls. A separate coating of a three-way catalyst is provided over the zeolite coating. The trap may further include an oxygen storage material. The hydrocarbon trap may be positioned in the exhaust gas system of a vehicle such that unburnt hydrocarbons are adsorbed on the trap and stored until the monolith reaches a sufficient temperature for catalyst activation.