摘要:
Method of synthesis for a material made of particles having a core and a coating and/or being connected to each other by carbon cross-linking, the core of these particles containing at least one compound of formula LixM1−yM′y(XO4)n, in which x,y and n are numbers such as 0≦x≦2, 0≦y≦0.6 and 1≦n≦1.5, M is a transition metal, M′ is an element with fixed valency, and the synthesis is carried out by reaction and bringing into equilibrium the mixture of precursors, with a reducing gaseous atmosphere, in such a way as to bring the transition metal or metals to the desired valency level, the synthesis being carried out in the presence of a source of carbon called carbon conductor, which is subjected to pyrolysis. The materials obtained have excellent electrical conductivity as well as very improved chemical activity.
摘要翻译:由具有芯和涂层的颗粒和/或通过碳交联彼此连接的材料制成的材料的合成方法,这些颗粒的芯含有至少一种式Li x x的化合物, 其中x,y和n是数字,其中x,y和n是数字,其中x,y和n是数字, 例如0 <= x <= 2,0 <= y <= 0.6和1 <= n <= 1.5,M是过渡金属,M'是具有固定价态的元素,合成通过反应和 使前体的混合物与还原性气体气氛以使过渡金属或金属达到所需化合价水平的方式达到平衡,该合成是在称为碳导体的碳源的存在下进行的,其中 经受热解。 获得的材料具有优异的导电性以及非常改善的化学活性。
摘要:
Method of synthesis for a material made of particles having a core and a coating and/or being connected to each other by carbon cross-linking, the core of these particles containing at least one compound of formula LixM1−yM′y(XO4)n, in which x, y and n are numbers such as 0≦x≦2, 0≦y≦0.6 and 1≦n≦1.5, M is a transition metal, M′ is an element with fixed valency, and the synthesis is carried out by reaction and bringing into equilibrium the mixture of precursors, with a reducing gaseous atmosphere, in such a way as to bring the transition metal or metals to the desired valency level, the synthesis being carried out in the presence of a source of carbon called carbon conductor, which is subjected to pyrolysis. The materials obtained have excellent electrical conductivity, as well as very improved chemical activity.
摘要翻译:由具有芯和涂层的颗粒和/或通过碳交联彼此连接的材料制成的材料的合成方法,这些颗粒的芯含有至少一种式Li x x的化合物, 其中x,y和n是数字,其中x,y和n是数字,其中x,y和n是数字, 例如0 <= x <= 2,0 <= y <= 0.6和1 <= n <= 1.5,M是过渡金属,M'是具有固定价态的元素,合成通过反应和 使前体的混合物与还原性气体气氛以使过渡金属或金属达到所需化合价水平的方式达到平衡,该合成是在称为碳导体的碳源的存在下进行的,其中 经受热解。 获得的材料具有优异的导电性,以及非常改善的化学活性。
摘要:
The invention relates to a process for preparing an at least partially lithiated transition metal oxyanion-based lithium-ion reversible electrode material, which comprises providing a precursor of said lithium-ion reversible electrode material, heating said precursor, melting same at a temperature sufficient to produce a melt comprising an oxyanion containing liquid phase, cooling said melt under conditions to induce solidification thereof and obtain a solid electrode that is capable of reversible lithium ion deinsertion/insertion cycles for use in a lithium battery. The invention also relates to lithiated or partially lithiated oxyanion-based-lithium-ion reversible electrode materials obtained by the aforesaid process.
摘要:
The invention concerns ionic compounds in which the anionic load has been delocalized. A compound disclosed by the invention is comprised of an amide or one of its salts, including an anionic portion combined with at least one cationic portion M+m in sufficient numbers to ensure overall electronic neutrality; is the compound is further comprised of M as a hydroxonium, a nitrosonium NO+, an ammonium —NH4+, a metallic cation with the valence m, an organic cation with the valence m, or an organometallic cation with the valence m. The anionic portion matches the formula RF—SOx—N-Z, wherein RF is a perfluorinated group, x is 1 or 2, and Z is an electroattractive substituent. The compounds can be used notably for ionic conducting materials, electronic conducting materials, colorants, and the catalysis of various chemical reactions.
摘要:
The invention concerns novel ionic compounds with low melting point whereof the onium type cation having at least a heteroatom such as N, O, S or P bearing the positive charge and whereof the anion includes, wholly or partially, at least an ion imidide such as (FX1O)N−(OX2F) wherein X1 and X2 are identical or different and comprise SO or PF, and their use as solvent in electrochemical devices. Said composition comprises a salt wherein the anionic charge is delocalised, and can be used, inter alia, as electrolyte.
摘要翻译:本发明涉及具有低熔点的新型离子化合物,其中具有至少具有正电荷的N,O,S或P的杂原子的鎓型阳离子及其阴离子全部或部分至少包含一个离子酰亚胺,例如 (FX 1 O)N(O X 2 F)其中X 1和X 2相同或不同并且包含SO或PF,并且它们在电化学装置中用作溶剂。 所述组合物包含盐,其中阴离子电荷是离域的,并且可以特别地用作电解质。
摘要:
The invention is related to ionic compounds, derivatives of malononitrile, in which the anionic load has been displaced. An ionic compound disclosed by the invention includes an anionic portion combined with at least one cationic portion M+m in sufficient number to ensure overall electronic neutrality; the compound is further comprised of M as a hydroxonium, a nitrosonium NO+, an ammonium —NH4+, a metallic cation with the valence m, an organic cation with the valence m, or an organometallic cation with the valence m. The anionic portion corresponds to one of the formulas RD—Y—C(C≡N)2− or Z—C(C≡N)2− in which Z is an electroattractive group, RD is an organic radical, and Y is a carbonyl, a thiocarbonyl, a sulfonyl, a sulfinyl, or a phosphonyl. The compounds can be used notably for ionic conducting materials, electronic conducting materials, colorants, and the catalysis of various chemical reactions.
摘要:
An in-situ thermal management system for an energy storage device. The energy storage device includes a plurality of energy storage cells each being coupled in parallel to common positive and negative connections. Each of the energy storage cells, in accordance with the cell's technology, dimensions, and thermal/electrical properties, is configured to have a ratio of energy content-to-contact surface area such that thermal energy produced by a short-circuit in a particular cell is conducted to a cell adjacent the particular cell so as to prevent the temperature of the particular cell from exceeding a breakdown temperature. In one embodiment, a fuse is coupled in series with each of a number of energy storage cells. The fuses are activated by a current spike capacitively produced by a cell upon occurrence of a short-circuit in the cell, thereby electrically isolating the short-circuited cell from the common positive and negative connections.
摘要:
These additives are represented by the following general formula: L—Y—S in which L designates a hydrocarbon radical which serves as lubricating segment; S designates an oligomer segment which serves as solvating segment of metallic salts and Y designates a chemical bond which joins the hydrocarbon radical and the oligomer segment. With these additives there is no more need to subsequently wash the surface of laminated lithium.
摘要:
The invention relates to ionic compounds in which the anionic load has been displaced, and the uses of these compounds. A compound disclosed by the invention comprises an anionic portion combined with at least one cationic portion M+m in sufficient numbers to ensure overall electronic neutrality. The anionic portion is comprised of one of the groups (A) and (B): wherein Y1, Y2, Y3, Y4 and Y5 represent a carbonyl group, a sulfonyl group, a thiocarbonyl group, a thionyl group, a —C(═NCN)— or a —C(═C(CN)2)— group; Z represents an electroattractive radical; each of the substituents, RA, RB, RC and RD represents independently of one another a monovalent or divalent organic radical or is part of a polymer chain, with at least one of the substituents RC and RD being a perfluorinated radical. The compounds can be used especially for ionic conducting materials, electronic conducting materials, colorants, and the catalysis of various chemical reactions.
摘要:
There is provided a mother-battery containing at least the following films: an anode of metallic lithium or sodium, a polymer electrolyte which is conductive towards the alkaline ions of the anode and also acts as a separator between the electrodes, and a composite cathode consisting of a compound which is reducible to lithium or sodium, an additive of electronic conduction and a polymer electrolyte binder. The mother battery also includes an electronically conductive thin coating on the external face of the anode and, possibly of the cathode, in which the conductive material is chemically inert towards the electrode material and which also serves to establish permanent electrical contacts on the external faces. The laminated mother-battery of larger surface area and at least partially charged is thereafter subjected to a sharp mechanical cutting out to give thin polymer electrolyte batteries with lithium or sodium anode. The thus cut out batteries preserve substantially their voltage after mechanical cutting out which is recovered by a mechanism of self-healing.