Process of etching a titanium/tungsten surface and etchant used therein
    5.
    发明授权
    Process of etching a titanium/tungsten surface and etchant used therein 有权
    蚀刻钛/钨表面和其中使用的蚀刻剂的工艺

    公开(公告)号:US07425278B2

    公开(公告)日:2008-09-16

    申请号:US11563858

    申请日:2006-11-28

    IPC分类号: C23C1/00

    CPC分类号: H01L21/32134

    摘要: An etchant which includes an aqueous solution of between about 30% and about 38% concentrated hydrogen peroxide, said percentages being by volume, based on the total volume of the solution; between about 3.5 ml and about 20 ml per liter of phosphoric acid; and an amount of potassium hydroxide to adjust the pH of the solution to between about 7.8 and about 9.1. The etchant is useful in removing a layer of an alloy of titanium and tungsten or a layer of tungsten from a precision surface.

    摘要翻译: 包括约30%至约38%浓缩的过氧化氢的水溶液的蚀刻剂,所述百分比基于溶液的总体积计; 约3.5ml至约20ml /升磷酸; 和一定量的氢氧化钾以将溶液的pH调节至约7.8至约9.1。 蚀刻剂可用于从精密表面去除钛和钨的合金层或钨层。

    Method and process for reducing undercooling in a lead-free tin-rich solder alloy
    10.
    发明授权
    Method and process for reducing undercooling in a lead-free tin-rich solder alloy 有权
    在无铅富锡焊料合金中减少过冷的方法和工艺

    公开(公告)号:US07784669B2

    公开(公告)日:2010-08-31

    申请号:US12536122

    申请日:2009-08-05

    IPC分类号: B23K35/24

    摘要: Briefly, a novel material process is disclosed wherein one or more nucleation modifiers are added, in trace amounts, to a lead-free tin-rich solder alloy to produce a solder composition with reduce or suppressed undercooling temperature characteristics. The modifier being a substance which facilitates the reduction of extreme anisotropic properties associated with body-centered-tetragonal tin based lead-free solder. The addition of the nucleation modifiers to the solder alloy does not materially effect the solder composition's melting point. As such, balls of solder with the nucleated composition freeze while other solder balls within the array remain in the melt. This effectively enables one substrate to be pinned to another substrate by one or more predetermined solder balls to secure the package while the remaining solder joints are in the liquid state. Further, the addition of a trace amount of nucleation sites within the composition facilitates control over the number, size, and orientations of primary intermetallic compounds in tin rich crystallite grains. Moreover, trace amounts of one or more solid and/or insoluble nucleating modifiers within a given volume of solder reduces the size of average crystallites within the composition.

    摘要翻译: 简而言之,公开了一种新颖的材料方法,其中将一种或多种成核改性剂以微量添加到无铅富锡焊料合金中以产生具有降低或抑制的过冷温度特性的焊料组合物。 该改性剂是有助于减少与体心四方锡锡基无铅焊料相关的极端各向异性的物质。 将成核改性剂添加到焊料合金中不会实质上影响焊料组合物的熔点。 因此,具有成核组合物的焊料球冻结,而阵列内的其它焊球保持在熔体中。 这有效地使一个基板通过一个或多个预定的焊球被固定到另一个基板,以固定封装,而剩余的焊点处于液态。 此外,在组合物中添加微量的成核位点有助于控制富锡微晶颗粒中初级金属间化合物的数量,尺寸和取向。 此外,在给定体积的焊料中痕量的一种或多种固态和/或不溶性成核改性剂减少了组合物内平均微晶的尺寸。